“Silapillar[n]arenes: Their Enhanced Electronic Conjugation and Conformational Versatility”
Ohtani, S.; Akine, S.; Kato, K.; Fa, S.; Shi, T.-H.; Ogoshi, T.
J. Am. Chem. Soc.2024, 146, 4695–4703.
doi: 10.1021/jacs.3c12093
“Induced chirality at the surface: fixation of a dynamic M/P invertible helical Co3 complex on SiO2”
Muratsugu, S.; Sawaguchi, K.; Shiraogawa, T.; Chiba, S.; Sakata, Y.; Shirai, S.; Baba, H.; Ehara, M.; Akine, S.; Tada, M.
Chem. Commun.2024, 60, 2094–2097.
doi: 10.1039/D3CC05534E
“Friedel–Crafts Acylation for Accessing Multi-Bridge-Functionalized Large Pillar[n]arenes”
Shi, T.-H.; Akine, S.; Ohtani, S.; Kato, K.; Ogoshi, T.
Angew. Chem. Int. Ed.2024, 63, e202318268. (Selected as a Hot Paper)
doi: 10.1002/anie.202318268
“Acceleration and deceleration of chirality inversion speeds in a dynamic helical metallocryptand by alkali metal ion binding”
Ikbal, S. A.; Zhao, P.; Ehara, M.; Akine, S.
Sci. Adv.2023, 9, eadj5536.
doi: 10.1126/sciadv.adj5536
“Stapling strategy for slowing helicity interconversion of α-helical peptides and isolating chiral auxiliary-free one-handed forms”
Ousaka, N.; MacLachlan, M. J.; Akine, S.
Nature Commun.2023, 14, 6834.
doi: 10.1038/s41467-023-42493-y
“Dynamic-to-Static Planar Chirality Conversion in Pillar[5]arenes Regulated by Guest Solvents or Amplified by Crystallization”
Wada, K.; Suzuki, M.; Kakuta, T.; Yamagishi, T.-a.; Ohtani, S.; Fa, S.; Kato, K.; Akine, S.; Ogoshi, T.
Angew. Chem. Int. Ed.2023, 62, e202217971.
(Selected as a Hot Paper; Highlighted in the Inside Front Cover)
doi:10.1002/anie.202217971
“Adaptive Planar Chirality of Pillar[5]arenes Invertible by n-Alkane Lengths”
Adachi, K.; Fa, S.; Wada, K.; Kato, K.; Ohtani, S.; Nagata, Y.; Akine, S.; Ogoshi, T.
J. Am. Chem. Soc.2023, 145, 8114–8121.
doi:10.1021/jacs.3c01019
“Speed Tuning of the Formation/Dissociation of a Metallorotaxane”
Sakata, Y.; Nakamura, R.; Hibi, T.; Akine, S.
Angew. Chem. Int. Ed.2023, 62, e202217048.
doi:10.1002/anie.202217048
“Synthesis of amphiphilic chiral salen complexes and their conformational manipulation at the air–water interface”
Akine, S.; Nomura, K.; Takahashi, M.; Sakata, Y.; Mori, T.; Nakanishi, W.; Ariga, K.
Dalton Trans.2023, 52, 260-268.
(Highlighted as the Front Cover)
doi:10.1039/D2DT03201E
“Synthesis of Isomeric Tb3+–Phthalocyanine Double-Decker Complexes
Depending on the Difference in the Direction of Coordination Plane and Their Magnetic Properties”
Yamada, Y.; Nakajima, H.; Kobayashi, C.; Shuku, Y.; Awaga, K.; Akine, S.; Tanaka, K.
Chem. Eur. J.2023, 29, e202203272.
(Highlighted as the Front Cover)
doi.org/10.1002/chem.202203272
“A Twisted Chiral Cavitand with 5-Fold Symmetry and Its Length-Selective Binding Properties”
Shi, T.-H.; Nagata, Y.; Akine, S.; Ohtani, S.; Kato, K.; Ogoshi, T.
J. Am. Chem. Soc.2022, 144, 23677-23684.
(Highlighted as the Supplementary Cover)
doi:10.1021/jacs.2c09589
“Rotaxane formation by an allosteric pseudomacrocyclic anion receptor utilising kinetically labile copper(I) coordination properties”
Aizawa, T.; Akine, S.; Saiki, T.; Nakamura, T.; Nabeshima, T.
Dalton Trans.2022, 51, 17277-17282.
doi:10.1039/D2DT03331C
“Real-time chirality transfer monitoring from statistically random to discrete homochiral nanotubes”
Fa, S.; Shi, T.-h.; Akama, S.; Adachi, K.; Wada, K.; Tanaka, S.; Oyama, N.; Kato, K.; Ohtani, S.; Nagata, Y.;
Akine, S.; Ogoshi, T.
Nat. Commun.2022, 13, 7378.
doi.org/10.1038/s41467-022-34827-z
“π-Stacked Ion Pairs: Tightly Associated Charged Porphyrins in Ordered Arrangement Enabling Radical-Pair Formation”
Tanaka, H.; Kobayashi, Y.; Furukawa, K.; Okayasu, Y.; Akine, S.; Yasuda, N.; Maeda, H.
J. Am. Chem. Soc.2022, 144, 21710-21718.
(Highlighted as the Supplementary Cover)
doi:10.1021/jacs.2c09589
“Noncooperative guest binding by metal-free [2 + 2] Schiff-base macrocycles”
Chaudhry, M. T.; Patrick, B. O.; Akine, S.; MacLachlan, M. J.
Org. Biomol. Chem.2022, 20, 8259–8268.
doi:10.1039/D2OB01511K
“State- and water repellency-controllable molecular glass of pillar[5]arenes with fluoroalkyl groups by guest vapors”
Onishi, K.; Ohtani, S.; Kato, K.; Fa, S.; Sakata, Y.; Akine, S.; Ogasawara, M.; Asakawa, H.; Nagano, S.;
Takashima, Y.; Mizuno, M.; Ogoshi, T.
Chem. Sci.2022, 13, 4082-4087.
doi:10.1039/D2SC00828A
“Transient chirality inversion during racemization of ahelical cobalt(III) complex”
Sakata, Y.; Chiba, S.; Akine, S.
Proc. Natl. Acad. Sci. USA2022, 119, e2113237119.
doi:10.1073/pnas.2113237119
“Synthesis of Pentaarylcyclobutenylrhodium(I) Complexes and Their Reactivity and Initiation Mechanism in Polymerization of Monosubstituted Acetylenes”
Sakamoto, S.; Taniguchi, T.; Sakata, Y.; Akine, S.; Nishimura, T.; Maeda, K.
Organometallics2022, 41, 472–479.
doi:10.1021/acs.organomet.1c00712
“Metal-dependent selective formation of calix[4]arene assemblies based on dynamic covalent chemistry”
Sakata, Y.; Tsuyuki, R.; Sugimoto, S.; Akine, S.
Chem. Commun., 2021, 57, 13510-13513.
(Highlighted as the Outside Back Cover)
doi:10.1039/D1CC05553D
“Synthesis of a monocationic μ-nitrido-bridged iron porphycene dimer and its methane oxidation activity”
Yamada, Y.; Miwa, Y.; Toyoda, Y.; Yamaguchi, T.; Akine, S.; Tanaka, K.
Dalton Trans., 2021, 50, 16775-16781.
doi:10.1039/D1DT02922C
“Rhodium(I) Complexes Bearing an Aryl-Substituted 1,3,5-Hexatriene Chain: Catalysts for Living Polymerization of Phenylacetylene and Potential Helical Chirality of 1,3,5-Hexatrienes”
Sakamoto, S.; Taniguchi, T.; Sakata, Y.; Akine, S.; Nishimura, T.; Maeda, K.
Angew. Chem. Int. Ed., 2021, 60, 22201-22206
doi:10.1002/anie.202108032
“Application of μ-Nitrido- and μ-Carbido-Bridged Iron Phthalocyanine Dimers as Cathode-Active Materials for Rechargeable Batteries”
Shimizu, T.; Wakamatsu, K.; Yamada, Y.; Toyoda, Y.; Akine, S.; Yoza, K.; Yoshikawa, H.
ACS Appl. Mater. Interfaces, 2021, 13, 40612–40617.
doi:10.1021/acsami.1c10540
“Enhancement of Alkali Metal Ion Recognition by Metalation of a Tris(saloph) Cryptand Having Benzene Rings at the Bridgeheads”
Akine, S.; Miyashita, M.; Nabeshima, T.
Inorg. Chem., 2021, 60, 12961-12971.
(Highlighted as the Supplementary Cover)
doi:10.1021/acs.inorgchem.1c01376
“A chiral spirobifluorene-based bis(salen) zinc(II) receptor towards highly enantioselective binding of chiral carboxylates”
Ikbal, S. A.; Sakata, Y.; Akine, S.
Dalton Trans., 2021, 50, 4119-4123.
(Highlighted as the Back Cover)
doi:10.1039/D1DT00218J
“Exclusive formation of a meridional complex of a tripodand and perfect suppression of guest recognition”
Morita, H.; Akine, S.; Nakamura, T.; Nabeshima, T.
Chem. Commun., 2021, 57, 2124-2127.
(Highlighted as the Front Cover)
doi:10.1039/D1CC00146A
“Synthesis and Crystal Structure of (μ-Acetato)bis(μ-Alkoxo)dicobalt(II, III) Complex
with an Unsymmetric Dinucleating Ligand”
Shinde, N.; Handa, R.; Furutachi, H.; Sakata, Y.; Akine, S.; Fujinami, S.; Suzuki, M.
X-ray Struct. Anal. Online, 2021, 37, 13-14.
doi:10.2116/xraystruct.37.13
“Guest Recognition Control Accompanied by Stepwise Gate Closing and Opening of a Macrocyclic Metallohost”
Sakata, Y.;Okada, M.; Akine, S.
Chem. Eur. J.2021, 27, 2284–2288.
(Highlighted as the Inside Cover).
doi:10.1002/chem.202004487
“Vapoluminescence Behavior Triggered by Crystal-State Complexation between Host Crystals and Guest Vapors Exhibiting No Visible Fluorescence”
Ogoshi, T.; Hamada, Y.; Sueto, R.; Kojima, R.; Sakakibara, F.; Nagata, Y.; Sakata, Y.; Akine, S.; Ono, T.; Kakuta, T.; Yamagishi, T.-a.
Cryst. Growth Des.2020, 20, 7087–7092.
(Highlighted as the Supplementary Cover).
doi:10.1021/acs.cgd.0c00982
“Efficient formation of [3]pseudorotaxane based on cooperative complexation of dibenzo-24-crown-8 with diphenylviologen axle”
Sakata, Y.; Ogura, T.; Akine, S.
Chem. Commun.2020, 56, 8735-8738.
(Highlighted as the Front Cover; Themed collection of 2020 emerging investigators).
doi:10.1039/D0CC03131C
“Crystal Structure of (μ-Phenoxo)bis(μ-pentafluorobenzoate)dicobalt(II, III) Complex with a Dinucleating Ligand”
Shinde, N.; Furutachi, H.; Sakata, Y.; Akine, S.; Fujinami, S.; Suzuki, M.
X-ray Struct. Anal. Online2020, 36, 23-25.
doi:10.2116/xraystruct.36.23
“Post‐Metalation Modification of a Macrocyclic Dicobalt(III) Metallohost by Site‐Selective Ligand Exchange for Guest Recognition Control”
Sakata, Y.; Okada, M.; Tamiya, M.; Akine, S.
Chem. Eur. J.2020, 26, 7595-7601.
(Highlighted as the Inside Cover).
doi:10.1002/chem.202001072
“Non‐Covalent Interactions Enable the Length‐Controlled Generation of Discrete Tubes Capable of Guest Exchange”
Fa, S.; Sakata, Y.; Akine, S.; Ogoshi, T.
Angew. Chem. Int Ed.2020, 59, 9309-9313.
doi:10.1002/anie.201916515
“Macrocyclic dimer of Fc(NHC(O)PPh2-AuCl)2 induced by aurophilic interactions, and chirality induction into Fc core”
Matsutani, T.; Itazaki, M.; Akine, S.; Moriuchi, T.
J. Organomet. Chem.2020, 912, Article 121182.
doi:10.1016/j.jorganchem.2020.121182
“ON/OFF Control of the Flipping Motion of Diuranyl Bis(Salophen) Macrocycle by Extremely Strong Binding with Fluoride Ion”
Cametti,M.; Sakata, Y.; Martí-Rujas, J.; Akine, S.
Inorg. Chem.2019, 58, 14871-14875.
doi:10.1021/acs.inorgchem.9b02587
“Switching of Recognition First and Reaction First Mechanisms
in Host–Guest Binding Associated with Chemical Reactions”
Sakata, Y.; Tamiya, M.; Okada, M.; Akine, S.
J. Am. Chem. Soc.2019, 141, 15597-15604.
doi:10.1021/jacs.9b06926
“Ring−Chain Competition in Supramolecular Polymerization Directed by Molecular Recognition of the Bisporphyrin Cleft”
Hirao, T.; Hisano, N.; Akine, S.; Kihara, S.; Haino, T.
Macromolecules2019, 52, 6160−6168.
doi:10.1021/acs.macromol.9b01012
“Functionalized metallonanobelt derivatives having quinoxaline scaffold prepared from a common precursor”
Sakata, Y.; Furukawa, Y.; Akine, S.
Tetrahedron Lett.2019, 60, 2049–2053
(Highlighted in the Front Cover).
doi:10.1016/j.tetlet.2019.06.057
“Synthesis and Crystal Structure of the Bis(μ-hydroxo)diiron(II) Complex
with Tridentate Ligands Having a Sterically Bulky Imidazolyl Group”
Yaguchi, R.; Furutachi, H.; Shirotsuki, S.; Zhang, X.; Ishikawa, T.; Akine, S.; Tosha, T.; Fujinami, S.; Suzuki, M.; Kitagawa, T.
X-ray Struct. Anal. Online2019, 35, 27–29.
doi:10.2116/xraystruct.35.27
“Crystal Structure of Bis(μ-hydroxo)diiron(III) Complex with Tripodal Ligands
Having a Terminal Carboxylate Group”
Zhang, Xi; Furutachi, H.; Ohyama, Y.; Fujinami, S.; Akine, S.; Suzuki, M.
X-ray Struct. Anal. Online2019, 35, 17–19.
doi:10.2116/xraystruct.35.17
“Crystal Structure of μ-Phenoxo-μ-benzoate-bridged Dinuclear Fe(II) Complex
with a Dinucleating Ligand Having a Sterically Bulky Imidazolyl Group”
Yasuda, Y.; Furutachi, H.; Hayashi, Y.; Fujinami, S.; Akine, S.; Suzuki, M.; Nagatomo, S.; Kitagawa, T.
X-ray Struct. Anal. Online2019, 35, 11–13.
doi:10.2116/xraystruct.35.11
“Ligand Exchange Strategy for Tuning of Helicity Inversion Speeds of Dynamic Helical Tri(saloph) Metallocryptands”
Sakata, Y.; Chiba S.; Miyashita, M.; Nabeshima, T.; Akine, S.
Chem. Eur. J.2019, 25, 2962-2966.
(
Selected as a Front Cover; Highlighted in a
Cover Profile Page
)
doi:10.1002/chem.201805799
“Host–Guest Complexation Using Pillar[5]arene Crystals:
Crystal‐Structure Dependent Uptake, Release, and Molecular Dynamics of an Alkane Guest”
Ogoshi, T.; Hamada, Y.; Sueto, R.; Sakata, Y.; Akine, S.; Moeljadi, A. M. P.; Hirao, H.; Kakuta, T.;
Yamagishi, T.-a.; Mizuno, M.
Chem. Eur. J.2019, 25, 2497-2502.
(
Hot Paper; Selected as a Front Cover; Highlighted in a
Cover Profile Page
)
doi:10.1002/chem.201805733
“Molecular weight fractionation by confinement of polymer in one-dimensional pillar[5]arene channels”
Ogoshi, T.; Sueto, R.; Yagyu, M.; Kojima, R.; Kakuta, T.; Yamagishi, T.-a.
Doitomi, K.; Tummanapelli, A. K.; Hirao, H.; Sakata, Y.; Akine, S.; Mizuno, M.
Nature Commun.2019, 10, 479.
doi:10.1038/s41467-019-08372-1
“A Closed Metallomolecular Cage that can Open its Aperture by Disulfide Exchange”
Akine, S.; Miyashita, M.; Nabeshima, T.
Chem. Eur. J.2019, 25, 1432-1435.
(
Selected as a Front Cover; Highlighted in a
Cover Profile Page
)
doi:10.1002/chem.201805359
“Crystal Structure of Bis(μ-hydroxo)diiron(II) Complex with a Dinucleating Ligand Having a Butyl Linker”
Sekino, M.; Furutachi, H.; Tasaki, K. Ishikawa, T.; Fujinami, S.; Akine, S.; Sakata, Y.; Suzuki, M.;
Nomura, T.; Ogura, T.; Kitagawa, T.
X-ray Struct. Anal. Online2019, 35, 5-7.
doi:10.2116/xraystruct.35.5
“Metallonanobelt: A Kinetically Stable Shape-Persistent Molecular Belt Prepared by Reversible Self-Assembly Processes”
Sakata, Y.; Yamamoto, R.; Saito, D.; Tamura, Y.; Maruyama, K.; Ogoshi, T.;Akine, S.
Inorg. Chem.2018, 57, 15500-15506.
(
Selected as a Supplementary Cover
)
doi:10.1021/acs.inorgchem.8b02804
“A novel graphite-like stacking structure in a discrete molecule and its molecular recognition behavior”
Akine, S.; Onuma, T.; Nabeshima, T.
New J. Chem.2018, 42, 9369-9372.
(
Highlighted as an outside back cover
)
doi:10.1039/C8NJ01315B
“Separation of Linear and Branched Alkanes Using Host–Guest Complexation of
Cyclic and Branched Alkane Vapors by Crystal State Pillar[6]arene”
Ogoshi, T.; Saito, K.; Sueto, R.; Kojima, R.; Hamada, Y.; Akine, S.;
Moeljadi, A. M. P.; Hirao, H.; Kakuta, T.; Yamagishi, T.-a.
Angew. Chem. Int. Ed.2018, 57, 1592-1595.
doi:10.1002/anie.201711575
“Response speed control of helicity inversion based on a "regulatory enzyme"-like strategy”
Sairenji, S.; Akine, S.; Nabeshima, T.
Sci. Rep.2018, 8, 137.
doi:10.1038/s41598-017-16503-1
“New mechanistic insights into intramolecular aromatic ligand hydroxylation and
benzyl alcohol oxidation initiated by the well-defined (µ-peroxo)diiron(III) complex”
Sekino, M.; Furutachi, H.; Tojo, R.; Hishi, A.; Kajikawa, H.; Suzuki, T.; Suzuki, K.;
Fujinami, S.; Akine, S.; Sakata, Y.; Ohta, T.; Hayami, S.; Suzuki, M.
Chem. Commun.2017, 53, 8838–8841.
(Highlighted as an inside front cover;
featured as a HOT Article for July, 2017
)
doi:10.1039/c7cc04382a
“Anion-capped metallohost allows extremely slow guest uptake and on-demand acceleration of guest exchange”
Sakata, Y.; Murata, C.; Akine, S.
Nature Commun.2017, 8, 16005.
doi:10.1038/ncomms16005
“Two-step modulation of ion recognition using a bis(saloph)-macrocyclic host having a 24-crown-8-like cavity”
Sakata, Y.; Kobayashi, S.; Akine, S.
Chem. Commun.2017, 53, 6363–6366.
doi:10.1039/C7CC02641B
“Alkane-Shape-Selective Vapochromic Behavior Based on
Crystal-State Host–Guest Complexation of Pillar[5]arene Containing One Benzoquinone Unit”
Ogoshi, T.; Shimada, Y.; Sakata, Y.; Akine, S.; Yamagishi, T.
J. Am. Chem. Soc.2017, 139, 5664–5667.
doi:10.1021/jacs.7b00631
“A Metallo-molecular Cage That Can Close the Apertures with Coordination Bonds”
Akine, S.; Miyashita, M.; Nabeshima, T.
J. Am. Chem. Soc.2017, 139, 4631–4634.
doi:10.1021/jacs.7b00840
"Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines"
Mihara, N.; Yamada, Y.; Akine, S.; Sugimoto, K.; Tanaka, K.
Chem. Commun.2017, 53, 2230-2232. (Highlighted as inside back cover)
doi:10.1039/C6CC09590A
"Lanthanide contraction for helicity fine-tuning and helix-winding control of single-helical metal complexes"
Sairenji, S.; Akine, S.; Nabeshima, T.
Dalton Trans.2016, 45, 14902-14906.
doi:10.1039/C6DT02635D
"Synthesis, Ion Recognition Ability, and Metal-Assisted Aggregation Behavior of
Dinuclear Metallohosts Having a Bis(Saloph) Macrocyclic Ligand"
Akine, S.; Utsuno, F.; Piao, S.; Orita, H.; Tsuzuki, S.; Nabeshima, T.
Inorg. Chem.2016, 55, 810-821.
doi:10.1021/acs.inorgchem.5b02288
"New mechanistic insight into intramolecular arene hydroxylation initiated
by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands"
Sekino, M.; Furutachi, H.; Tasaki, K.; Ishikawa, T.; Mori, S.; Fujinami, S.;
Akine, S.; Sakata, Y.; Nomura, T.; Ogura, T.; Kitagawa, T.; Suzuki, M.
Dalton Trans.2016, 45, 469-473.
doi:10.1039/C5DT04088D
"Solvent-Dependent Dual-Mode Photochromism between T- and P-Types in a Dipyrrinone Derivative"
Sakata, Y.; Fukushima, S.; Akine, S.; Setsune, J.-i.
Chem. Commun.2016, 52, 1278-1281.
doi:10.1039/C5CC07625K
"π-Electron Systems That Form Planar and Interlocked Anion Complexes
and Their Ion-Pairing Assemblies"
Yamakado, R.; Sakurai, T.; Matsuda, W.; Seki, S.; Yasuda, N.; Akine, S.; Maeda, H.
Chem. Eur. J., 2016, 22, 626-638.
doi:10.1002/chem.201503654
"Overcoming Statistical Complexity: Selective Coordination of Three Different Metal Ions
to a Ligand with Three Different Coordination Sites"
Akine, S.; Matsumoto, T.; Nabeshima, T.
Angew. Chem. Int. Ed.2016, 55, 960-964
(Hot Paper; highlighted as an Inside Back Cover).
doi:10.1002/anie.201508065
"Synthesis of tetrafunctionalized pentiptycenequinones for construction of
cyclic dimers with a cylindrical shape by boronate ester formation"
Akine, S.; Kusama, D.; Takatsuki, Y.; Nabeshima, T.
Tetrahedron Lett.2015, 56, 4880–4884.
doi:10.1016/j.tetlet.2015.06.070
"Host–Guest Complexation of Perethylated Pillar[5]arene with Alkanes in the Crystal State"
Ogoshi, T.; Sueto, R.; Yoshikoshi, K. Sakata, Y.; Akine, S.; Yamagishi, T.
Angew. Chem. Int. Ed.2015, 54, 9849-9852.
doi:10.1002/anie.201503489
"Oxidation Reactivity of a Structurally and Spectroscopically Well-Defined
Mononuclear Peroxocarbonato-Iron(III) Complex"
Tsugawa, T.; Furutachi, H.; Marunaka, M.; Endo, T.; Hashimoto, K.; Fujinami, S.;
Akine, S.; Sakata, Y.; Nagatomo, S.; Tosha, T.; Nomura, T.; Kitagawa, T.; Ogura, T.; Suzuki, M.
Chem. Lett.2015, 44, 330-332.
doi:10.1246/cl.141058
“Increased Nuclearity of Saleln-Type Transition Metal Complexes by Incorporation of
O-Alkyloxime Functionality”
Akine, S.; Nabeshima, T.
Heteroatom Chem.2014, 25, 410-421.
doi:10.1002/hc.21205
“Dynamic helicity control of a single-helical oligooxime
complex and acid-base triggered repeated helicity inversion mediated
by amino acids”
Sairenji, S.; Akine, S.; Nabeshima, T.
Chem. Lett.2014, 43, 1107-1109.
doi:10.1246/cl.140263
“Dynamic helicity control of single-helical oligooxime metal
complexes by coordination of chiral carboxylate ions”
Sairenji, S.; Akine, S.; Nabeshima, T.
Tetrahedron Lett.2014, 55, 1987-1990.
doi:/10.1016/j.tetlet.2014.02.009
“Perfect encapsulation of guanidinium ion in a helical trinickel(II) metallocryptand
for efficient regulation of helix inversion rate”
Akine, S.; Miyashita, M.; Piao, S.; Nabeshima, T.
Inorg. Chem. Front.2014, 1, 53-57
(invited article in the first issue of this journal).
doi:10.1039/C3QI00067B
“Cage-like tris(salen)-type metallocryptand for cooperative guest recognition”
Akine, S.; Piao, S.; Miyashita, M.; Nabeshima, T.
Tetrahedron Lett.2013, 54, 6541-6544.
doi:10.1016/j.tetlet.2013.09.098
“Synthesis of Planar Metal Complexes and the Stacking Abilities of
Naphthalenediol-Based Acyclic and Macrocyclic Salen-Type Ligands”
Akine, S.; Varadi, Z.; Nabeshima, T.
Eur. J. Inorg. Chem.2013, 5987-5998.
doi:10.1002/ejic.201300917
“Stepwise Helicity Inversions by Multisequential Metal Exchange”
Akine, S.; Sairenji, S.; Taniguchi, T.; Nabeshima, T.
J. Am. Chem. Soc.2013, 135, 12948-12951.
doi:10.1021/ja405979v
“Programmed multiple complexation for the creation of helical structures
from acyclic phenol–bipyridine oligomer ligands”
Akine, S.; Nagumo, H.; Nabeshima, T.
Dalton Trans.2013, 42, 15974-15986.
doi:10.1039/c3dt51240a
“Ligand Modification of Cyclometalated Ruthenium Complexes
in the Aerobic Oxidative Dehydrogenation of Imidazolines”
Aiki, S.; Kijima, Y.; Kuwabara, J.; Taketoshi, A.; Koizumi, T.; Akine, S.; Kanbara, T.
ACS Catal.2013, 3, 812-816.
doi:10.1021/cs300811w
“Conformational Control of Electron-rich Calix[6]arene Skeleton by Paraquat Recognition”
Akine, S.; Kusama, D.; Nabeshima, T.
Tetrahedron Lett.2013, 54, 205-209.
doi:10.1016/j.tetlet.2012.10.105
“Oligometallic Template Strategy for Synthesis of a Macrocyclic
Dimer-type Octaoxime Ligand for Its Cooperative Complexation”
Akine, S.; Tadokoro, T.; Nabeshima, T.
Inorg. Chem.2012, 51, 11478-11486.
doi:10.1021/ic3012525
“Design and controlled emission properties of bioorganometallic
compounds composed of uracils and organoplatinum(II) moieties”
Moriuchi, T.; Sakamoto, Y.; Noguchi, S.; Fujiwara, T.; Akine, S.; Nabeshima, T.; Hirao, T.
Dalton Trans.2012, 41, 8524-8531
(selected as the inside cover picture).
doi:10.1039/c2dt30533j
“Hierarchical Helix of Helix in the Crystal: Formation of Variable-Pitch
Helical Pi-Stacked Array of Single-Helical Dinuclear Metal Complexes”
Akine, S.; Nagumo, H.; Nabeshima, T.
Inorg. Chem.2012, 51, 5506-5508.
doi:10.1021/ic3004273
“Remarkably Selective Recognition of Iodobenzene Derivatives by a Macrocyclic Bis-PtII Metallohost”
Trokowski, R.; Akine, S.; Nabeshima, T.
Chem. Eur. J.2011, 17, 14420-14428.
doi:10.1002/chem.201101650
“A Molecular Leverage for Helicity Control and Helix Inversion”
Akine, S.; Hotate, S.; Nabeshima, T.
J. Am. Chem. Soc.2011, 133, 13868-13871.
doi:10.1021/ja205570z
“Highly Cooperative Double Metalation of a Bis(N2O2) Ligand
Based on Bipyridine-Phenol Framework Driven by Intramolecular Pi-Stacking of Square Planar Nickel(II) Complex Moieties”
Akine, S.; Shimada, T.; Nagumo, H.; Nabeshima, T.
Dalton Trans.2011, 40, 8507-8509
(selected as the cover picture).
doi:10.1039/c1dt10124b
“Nuclearity Control of a Trisaloph Zinc Cluster Complex
Dependent on Minute Structural Differences in the Bridging Anions”
Yamamura, M.; Miyazaki, H.; Iida, M.; Akine, S.; Nabeshima, T.
Inorg. Chem.2011, 50, 5315-5317.
doi:10.1021/ic2002833
“Multistep Oligometal Complexation of the Macrocyclic Tris(N2O2) Hexaoxime Ligand”
Akine, S.; Sunaga, S.; Nabeshima, T.
Chem. Eur. J.2011, 17, 6853-6861.
doi:10.1002/chem.201100122
“Wheel-Shaped ErIIIZnII3 Single-Molecule Magnet:
A Macrocyclic Approach to Designing Magnetic Anisotropy”
Yamashita, A.; Watanabe, A.; Akine, S.; Nabeshima, T.; Nakano, M.; Yamamura, T.; Kajiwara, T.
Angew. Chem., Int. Ed.2011, 50, 4016-4019.
doi:10.1002/anie.201008180
“Synthesis of Acyclic Tetrakis- and Pentakis(N2O2) Ligands
for Single-helical Heterometallic Complexes with a Greater Number of Winding Turns”
Akine, S.; Matsumoto, T.; Sairenji, S.; Nabeshima, T.
Supramol. Chem.2011, 23, 106-112.
doi:10.1080/10610278.2010.514906
“Spontaneous Enrichment of One-handed Helices by Dissolution of
Quasiracemic Crystals of a Tetranuclear Single Helical Complex”
Akine, S.; Hotate, S.; Matsumoto, T.; Nabeshima, T.
Chem. Commun.2011, 47, 2925-2927.
doi:10.1039/c0cc04998k
“Picosecond-Pulse-Pumped Distributed-Feedback Thick-Film
Waveguide Blue Laser Using Fluorescent Brightener 135”
Watanabe, H.; So, H.; Oki, Y.; Akine, S.; Omatsu, T.
Jpn. J. Appl. Phys.2010, 49, 072105.
doi:10.1143/JJAP.49.072105
“Dinuclear Complexes of the N2O2 Oxime Chelate Ligand
with Zinc(II)–Lanthanide(III) as a Selective Sensitization System for Sm3+”
Akine, S.; Utsuno, F.; Taniguchi, T.; Nabeshima, T.
Eur. J. Inorg. Chem.2010, 3143-3152.
doi:10.1002/ejic.200901243
“Synthesis of Ag+-Selective Dipalladium(II) Metallohost Based on
O-Alkyloxime Bis(N2SO) Ligands”
Akine, S.; Akimoto, A.; Nabeshima, T.
Phosphorus Sulfur Silicon Relat. Elem.2010, 185, 1000-1007.
doi:10.1080/10426501003772110
“Modulation of Multimetal Complexation Behavior of Tetraoxime
Ligand by Covalent Transformation of Olefinic Functionalities”
Akine, S.; Kagiyama, S.; Nabeshima, T.
Inorg. Chem.2010, 49, 2141-2152.
doi:10.1021/ic9019926
“Highly Efficient Regulation of Cation Recognition and Promotion
of Self-assembly by Metalation of a Macrocyclic Bis(N2O2) Ligand with Nickel(II)”
Akine, S.; Utsuno, F.; Nabeshima, T.
Chem. Commun.2010, 46, 1029-1031.
(selected as the cover picture)
doi:10.1039/b915722k
"Selective Binding of Benzenediol Derivatives by Simultaneous Non-covalent Interactions
in Bis-Pt(II) Aza-aromatic Host–Guest System"
Trokowski, R.; Akine, S.; Nabeshima, T.
Dalton Trans.2009, 10359-10366.
doi:10.1039/b911602h
“Multiple Folding Structures Mediated by Metal Coordination of Acyclic Multidentate Ligand”
Akine, S.; Morita, Y.; Utsuno, F.; Nabeshima, T.
Inorg. Chem.2009, 48, 10670-10678.
doi:10.1021/ic901372k
“Visible and Near-infrared Luminescence of Helical Zinc(II)-Lanthanide(III) Trinuclear Complexes
Having Acyclic Bis(N2O2) Oxime Ligand”
Akine, S.; Utsuno, F.; Nabeshima, T.
IOP Conf. Ser.: Mater. Sci. Eng.2009, 1, 012009.
doi:10.1088/1757-8981/1/1/012009
“Spontaneous Formation of a Chiral Supramolecular Superhelix in the Crystalline State
Using a Single-Stranded Tetranuclear Metallohelicate”
Akine, S.; Matsumoto, T.; Nabeshima, T.
Chem. Commun.2008, 4604-4606.
doi:10.1039/b810426c
“Acyclic Bis(N2O2 chelate) Ligand for Trinuclear d-Block Homo- and Heterometal Complexes”
Akine, S.; Taniguchi, T.; Nabeshima, T.
Inorg. Chem.2008, 47, 3255-3264.
doi:10.1021/ic702255s
“A Novel Cis-Trans Isomerism Found in a Sulfur-Bridged PdII2AuI2
Tetranuclear Complex with [Pd(amine)2(thiolato)2]-type Building Units”
Taguchi, M.; Sameshima, Y.; Igashira-Kamiyama, A.; Akine, S.; Nabeshima, T.; Konno, T.
Chem. Lett.2008, 37, 244-245.
doi:10.1246/cl.2008.244
“Synthesis, Characterization and Molecular Recognition of a Bis-Platinum Terpyridine Dimer”
Trokowski, R.; Akine, S.; Nabeshima, T.
Chem. Commun.2008, 889-890
(Top 10 accessed article in February 2008).
doi:10.1039/b716459a
“Synthesis, Stability, and Complexation Behavior of
Isolable Salen-Type N2S2 and N2SO Ligands Based on Thiol and Oxime Functionalities”
Akine, S.; Akimoto, A.; Shiga, T.; Oshio, H.; Nabeshima, T.
Inorg. Chem.2008, 47, 875-885
(Most-Accessed Article for the first-quarter of 2008).
doi:10.1021/ic701525c
“Oligometallic Template Strategy for Ring-Closing Olefin Metathesis:
Highly Cis- and Trans-Selective Synthesis of a 32-Membered Macrocyclic Tetraoxime”
Akine, S.; Kagiyama, S.; Nabeshima, T.
Inorg. Chem.2007, 46, 9525-9527.
doi:10.1021/ic701585x
“Multi-metal complexation and partially templated synthesis of metal clusters
by using triangular trisaloph ligands”
Nabeshima, T.; Miyazaki, H.; Iwasaki, A.; Akine, S.; Saiki, T.; Ikeda, C.
Tetrahedron2007, 63, 3328-3333.
doi:10.1016/j.tet.2007.02.046
“Multi-Step Regulation of Anion Recognition by Rredox-Active Pseudocryptand”
Nabeshima, T.; Masubuchi, S.; Taguchi, N.; Akine, S.; Saiki, T.; Sato, S.
Tetrahedron Lett.2007, 48, 1595-1598.
doi:10.1016/j.tetlet.2006.12.143
“Helical Metallohost-Guest Complexes via Site-Selective Transmetalation of Homotrinuclear Complexes”
Akine, S.; Taniguchi, T.; Nabeshima, T.
J. Am. Chem. Soc.2006, 128, 15765-15774.
doi:10.1021/ja0646702
“Chiral Single-stranded Metallohelix: Metal-mediated Folding of Linear Oligooxime Ligand”
Akine, S.; Taniguchi, T.; Nabeshima, T.
Tetrahedron Lett.2006, 47, 8419-8422.
doi:10.1016/j.tetlet.2006.09.125
“Guest-dependent Inversion Rate of a Tetranuclear Single Metallohelicate”
Akine, S.; Taniguchi, T.; Matsumoto, T.; Nabeshima, T.
Chem. Commun.2006, 4961-4963.
doi:10.1039/b610641b
“Efficient Formation of Homo and Hetero Metal Clusters
by Triangular Trisaloph Ligand as a Partial Template”
Nabeshima, T.; Miyazaki, H.; Iwasaki, A.; Akine, S.; Saiki, T.; Ikeda, C.; Sato, S.
Chem. Lett.2006, 35, 1070-1071.
doi:10.1246/cl.2006.1070
“Octanuclear Zinc(II) and Cobalt(II) Clusters Produced by
Cooperative Tetrameric Assembling of Oxime Chelate Ligands”
Akine, S.; Dong, W.; Nabeshima, T.
Inorg. Chem.2006, 45, 4677-4684.
doi:10.1021/ic060055n
“Heterometallic Zn2La and ZnLu Complexes Formed by
Site-selective Transmetalation of a Dimeric Homotrinuclear Zinc(II) Complex”
Akine, S.; Taniguchi, T.; Nabeshima, T.
Chem. Lett.2006, 35, 604-605.
doi:10.1246/cl.2006.604
“Tricyclic Pseudocryptand Formed by Reaction of FeII with Tripodand Bearing Triazacrown Ether”
Nabeshima, T.; Tanaka, Y.; Saiki, T.; Akine, S.; Ikeda, C.; Sato, S.
Tetrahedron Lett.2006, 47, 3541-3544.
doi:10.1016/j.tetlet.2006.03.084
“Stepwise and Dramatic Enhancement of Anion Recognition with a
Triple-site Receptor Based on the Calix[4]arene Framework Using Two Different Cationic Effectors”
Nabeshima, T.; Saiki, T.; Iwabuchi, J.; Akine, S.
J. Am. Chem. Soc.2005, 127, 5507-5511.
doi:10.1021/ja042882y
“Synthesis, Structures, and Magnetic Properties of Tri- and Dinuclear
Copper(II)-Gadolinium(III) Complexes of Linear Oligooxime Ligands”
Akine, S.; Matsumoto, T.; Taniguchi, T.; Nabeshima, T.
Inorg. Chem.2005, 44, 3270-3274.
doi:10.1021/ic0481677
“Novel Thiosalamo Ligand as a Remarkably Stable N2S2 Salen-type
Chelate and Synthesis of a Nickel(II) Complex”
Akine, S.; Nabeshima, T.
Inorg. Chem.2005, 44, 1205-1207.
doi:10.1021/ic048347g
“Oxime-Based Salen-Type Tetradentate Ligands with High Stability against Imine Metathesis Reaction”
Akine, S.; Taniguchi, T.; Dong, W.; Masubuchi, S.; Nabeshima, T.
J. Org. Chem.2005, 70, 1704-1711.
doi:10.1021/jo048030y
“Ca2+- and Ba2+-Selective Receptors Based on Site-Selective
Transmetalation of Multinuclear Polyoxime-Zinc(II) Complexes”
Akine, S.; Taniguchi, T.; Saiki, T.; Nabeshima, T.
J. Am. Chem. Soc.2005, 127, 540-541.
doi:10.1021/ja046790k
“Syntheses, Structures, and Properties of Quinone-Bridged Calix[6]arenes”
Akine, S.; Goto, K.; Kawashima, T.
Bull. Chem. Soc. Jpn.2005, 78, 169-179.
doi:10.1246/bcsj.78.169
“Cooperative Formation of Trinuclear Zinc(II) Complexes via
Complexation of a Tetradentate Oxime Chelate Ligand, Salamo, and Zinc(II) Acetate”
Akine, S.; Taniguchi, T.; Nabeshima, T.
Inorg. Chem.2004, 43, 6142-6144.
doi:10.1021/ic049282k
“Synthesis and Recognition Behavior of Multi-point Receptors
with Binding Sites for Different Metal Ions”
Saiki, T.; Iwabuchi, J.; Akine, S.; Nabeshima, T.
Tetrahedron Lett.2004, 45, 7007-7010.
doi:10.1016/j.tetlet.2004.07.140
“Homotropic Negative Allostery in Alkali Metal Ion Recognition by Biscalix[4]arene-based Receptor”
Nabeshima, T.; Saiki, T.; Sumitomo, K.; Akine, S.
Tetrahedron Lett.2004, 45, 6761-6763.
doi:10.1016/j.tetlet.2004.07.033
“Synthesis, Structure and Complexation Ability of Novel
Metalloreceptors Containing Two Pincer Complexes of Palladium(II)”
Nabeshima, T.; Nishida, D.; Akine, S.; Saiki, T.
Eur. J. Inorg. Chem.2004, 3779-3782.
(selected as the cover picture)
doi:10.1002/ejic.200400508
“Doubly Bridged Biscalix[4]arene for Homotropic and Heterotropic
Allosteric Effects on Ion Recognition”
Nabeshima, T.; Saiki, T.; Sumitomo, K.; Akine, S.
Tetrahedron Lett.2004, 45, 4719-4722.
doi:10.1016/j.tetlet.2004.04.088
“Synthesis and Structure of Polyhydroxyl Rigid Triangular
Nano-Macrocyclic Imine Having Multiple Hydrogen-Bonding Sites”
Akine, S.; Hashimoto, D.; Saiki, T.; Nabeshima, T.
Tetrahedron Lett.2004, 45, 4225-4227.
doi:10.1016/j.tetlet.2004.04.015
“Isolation and Structural Analysis of Novel Conformational
Isomers of the m-Xylylene-Bridged Calix[6]arenes: the "Partial Cone" and "Inverted Cone" Isomers”
Akine, S.; Goto, K.; Kawashima, T.
Tetrahedron Lett.2003, 44, 1171-1174.
doi:10.1016/S0040-4039(02)02833-2
“Remarkably Large Positive and Negative Allosteric Effects on
Ion Recognition by the Formation of a Novel Helical Pseudocryptand”
Nabeshima, T.; Yoshihira, Y.; Saiki, T.; Akine, S.; Horn, E.
J. Am. Chem. Soc.2003, 125, 28-29.
doi:10.1021/ja028750r
“Novel Synthetic Approach to Trinuclear 3d-4f Complexes: Specific Exchange of the
Central Metal of a Trinuclear Zinc(II) Complex of a Tetraoxime Ligand with a Lanthanide(III) Ion”
Akine, S.; Taniguchi, T.; Nabeshima, T.
Angew. Chem. Int. Ed.2002, 41, 4670-4673.
doi:10.1002/anie.200290011
“Transfer of Chiral Information through Achiral Ion Recognition
by a Novel Pseudocrown Ether with a Binaphthyl Moiety”
Nabeshima, T.; Hashiguchi, A.; Saiki, T.; Akine, S.
Angew. Chem. Int. Ed.2002, 41, 481-484.
doi:10.1002/1521-3773(20020201)41:3<481::AIDANIE481>3.0.CO;2-7
“Crystal structure of
15,85,105,125,195,215,245,275-octa-t-butyl-102,212,242,272-tetrakis((2-methoxy)ethoxy)-2,7,13,18-tetraoxa-4,15(5,2),5,16(2,5)-tetrapyridina-1,8,19(2,1,3),12(1,2,3),10,21,24,27(1,3)-dodecabenzenatricyclo[17.3.3.38,12]-octacosaphane
tetrakis(dichloromethane), (C124H152N4O12)(CH2Cl2)4”
Akine, S.; Sumitomo, K.; Nabeshima, T.
Z. Kristallogr. NCS2001, 216, 521-524.
doi:10.1524/ncrs.2001.216.14.555
“Synthesis and Crystal Structure of a Novel Triangular Macrocyclic Molecule,
Tris(H2saloph), and Its Water Complex”
Akine, S.; Taniguchi, T.; Nabeshima, T.
Tetrahedron Lett.2001, 42, 8861-8864.
doi:10.1016/S0040-4039(01)01943-8
“Conformational Mobility of the Bridged Calix[6]arenes with
Allyl and Ethyl Groups at the Lower Rim”
Akine, S.; Goto, K.; Kawashima, T.
Bull. Chem. Soc. Jpn.2001, 74, 2167-2174.
doi:10.1246/bcsj.74.2167
“Synthesis and Characterization of Novel Ligands 1,2-Bis(salicylideneaminooxy)ethanes”
Akine, S.; Taniguchi, T.; Nabeshima, T.
Chem. Lett.2001, 682-683.
doi:10.1246/cl.2001.682
“Synthesis and Reactions of Conformational Isomers of a Stable
Selenenic Acid Bearing a Bridged Calix[6]arene Framework”
Goto, K.; Saiki, T.; Akine, S.; Kawashima, T.; Okazaki, R.
Heteroatom Chem.2001, 12, 195-197.
doi:10.1002/hc.1031
“Control of Ion Binding by Cooperative Ion-Pair Recognition Using a Flexible Heterotopic Receptor”
Nabeshima, T.; Hanami, T.; Akine, S.; Saiki, T.
Chem. Lett.2001, 560-561.
doi:10.1246/cl.2001.560
“Structural Elucidation of 1,3-Phenylenebis(methylene)-Bridged
Calix[6]arenes with Four Uncapped Hydroxy Groups”
Saiki, T.; Akine, S.; Goto, K.; Tokitoh, N.; Kawashima, T.; Okazaki, R.
Bull. Chem. Soc. Jpn.2000, 73, 1893-1902.
doi:10.1246/bcsj.73.1893
“Synthesis, Structure, and Redox Properties of a Quinone-Bridged Calix[6]arene”
Akine, S.; Goto, K.; Kawashima, T.
Tetrahedron Lett.2000, 41, 897-901.
doi:10.1016/S0040-4039(99)02171-1
“Crystal Structures and Solvate Formation of Two
Conformationally Frozen Isomers of a Bridged Calix[6]arene”
Akine, S.; Goto, K.; Kawashima, T.
J. Inclusion Phenom. Macrocycl. Chem.2000, 36, 119-124.
doi:10.1023/A:1008104018173
“Different Aggregating Properties of Two Conformationally Frozen Isomers of
a Water-Soluble Bridged Calix[6]arene”
Akine, S.; Goto, K.; Kawashima, T.; Okazaki, R.
Bull. Chem. Soc. Jpn.1999, 72, 2781-2783.
doi:10.1246/bcsj.72.2781
“Micropolarity around a Zwitterionic Solvatochrome Covalently
Fixed in the Cavity of Bowl-Shaped Cyclophanes”
Akine, S.; Goto, K.; Okazaki, R.
Chem. Lett.1999, 681-682.
doi:10.1246/cl.1999.681
“Synthesis of Novel Water-soluble Molecular Bowls and Their
Unique Complexing Behavior with 1-Anilinonaphthalene-8-sulfonate”
Goto, K.; Akine, S.; Hayashi, T.; Okazaki, R.
Chem. Lett.1998, 291-292.
doi:10.1246/cl.1998.291
