金沢大学大学院自然科学研究科物質化学専攻
金沢大学理工学域物質化学類化学コース

有機化学研究分野 宇梶研究室

  • 金沢大学

 

発表論文

 

2022

1) Direct and Unified Access to Carbon Radicals from Aliphatic Alcohols by Cost-Efficient Titanium-Mediated Homolytic C−OH Bond Cleavage 

T. Suga, Y. Takahashi, C. Miki, Y. Ukaji  

Angew. Chem. Int. Ed. 2022, e202112533. https://doi.org/10.1002/anie.202112533

Highlighted in Organic Chemistry Portal

 

2) Highly (E)-Selective Trisubstituted Alkene Synthesis by Low-Valent Titanium-Mediated Homolytic Cleavage of Alcohol C−O Bond

T. Suga, R. Takada, S. Shimazu, M. Sakata, Y. Ukaji

J. Org. Chem. 2022, 87, 7487−7493. doi.org/10.1021/acs.joc.2c00246

 

3) Cyclopropenes for the Stepwise Synthesis of 1,2,4,5-Tetraarylbenzenes via 1,4-Cyclohexadienes 

S. Kishida, M. Takano, T. Sekiya, Y. Ukaji, K. Endo  

J. Org. Chem. 2022, 87, 14833−14839. doi.org/10.1021/acs.joc.2c01261

 

4) Formal Methylene Insertion into the C−H Bond of α-Carbonyl Aldonitrones with Dimethylsulfoxonium Methylide 

T. Sakurai, T. Yano, T. Suga, T. Soeta, Y. Ukaji  

Bull. Chem. Soc. Jpn. 2022, 95, 1518−1520. DOI:10.1246/bcsj.20220212

 

5) Hydroxy Group-Directed Diastereoselective Paterno`-Bu¨chi Reaction between Arylglyoxylates and Furfuryl Alcohols

Q. Wei, H. Ii, T. Suga, T. Soeta, H. Maeda, Y. Ukaji  

Chem. Lett. 2022, 51, 1143−1145. doi.org/10.1246/cl.220437

Featured in Org. Chem. Highlights

 

6) クリックケミストリーの源泉,Huisgen 反応

   ーーこの反応がなければ,クリックケミストリーは生まれなかった

宇梶 裕  

化学 2022, 77, 18−19.